January 2008, to be published in Physical Review B1


Specific heat of Sb: Isotopic and spin-orbit effects from measurements and \textit{ab initio} calculations
J. Serrano, R. K. Kremer, M. Cardona, G. Siegle, L. E. D{\i}az-S\'{a}nchez, and A. H. Romero

We report measurements of the specific heat $C$ of antimony crystals in the 2 -- 50~K temperature range for several isotopic compositions and {\em ab initio} calculations of the specific heat as a function of temperature. The contribution of spin-orbit interaction and the dependence of $C$ on isotopic mass are discussed and compared with previous observations reported for semiconductors and group VA semimetals. We also discuss the effect of spin-orbit interaction on the trigonal lattice parameter and the cohesive energy.

© 2008 The American Physical Society.